| 含醚键和萘环结构双马来酰亚胺的合成与表征 |
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| 引用本文： | 闫红强,王华清,程捷,方征平. 含醚键和萘环结构双马来酰亚胺的合成与表征[J]. 高分子材料科学与工程, 2011, 0(11): 1-3 |
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| 作者姓名： | 闫红强 王华清 程捷 方征平 |
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| 作者单位： | 浙江大学宁波理工学院高分子材料与工程研究所;浙江纺织服装职业技术学院; |
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| 基金项目： | 宁波市自然科学基金资助项目(2008A610058) |
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| 摘 要： | 利用分子设计的方法,以2,7-二羟萘为原料,利用四步反应合成出含有醚键和萘环结构的双马来酰亚胺单体（BMPN）。利用红外光谱（FT-IR）、核磁共振（1H-NMR）等方法表征了单体结构。利用热重分析（TG）研究了新型BMPN树脂的耐热性能。研究结果发现,新型BMPN树脂的Te是477.1℃,且在700℃时的残炭量高达6...
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| 关 键 词： | 双马来酰亚胺 醚键 萘环 合成 耐热性能 |
Synthesis and Characterization of the Bismaleimide Containing Ether Linkage and Naphthalene |
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| Hongqiang Yan,Huaqing Wang,Jie Cheng,Zhengping Fang. Synthesis and Characterization of the Bismaleimide Containing Ether Linkage and Naphthalene[J]. Polymer Materials Science & Engineering, 2011, 0(11): 1-3 |
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| Authors: | Hongqiang Yan Huaqing Wang Jie Cheng Zhengping Fang |
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| Affiliation: | Hongqiang Yan1,Huaqing Wang2,Jie Cheng1,Zhengping Fang1(1.Institute of Polymer Material and Engineering,Ningbo Institute of Technology,Zhejiang University,Ningbo 315100,China,2.Zhejiang Textile & Fashion Technology College,Ningbo 315211 China) |
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| Abstract: | Bismaleimide containing ether linkage and naphthalene(BMPN) was synthesized from 2,7-dihydroxynaphthalene and p-chloronitrobenzene by four-step method.The monomer of bismalemide was characterized by Fourier transform infrared spectrum(FT-IR) and 1H nuclear magnetic resonance spectrum(1H-NMR).The thermal stability of BMPN resin was studied by thermogravimetry(TG) measurements at a heating rate of 10 ℃/min in N2.The results indicate that Te of BMPN rsin is 477.1 ℃ and the anaerobic char yield is 63.8% at 700 ℃.It is illuminated that introduction of naphthalene can make up the loss of thermal properties due to the introduction of ether linkage and increases the anaerobic char yield at 700 ℃.Compared to BMP resin,thermal degradation rate of BMPN resin decreases. |
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| Keywords: | bismaleimide ether linkage naphthalene synthesis thermal properties |
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