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Improved photovoltaic performance of dye-sensitized solar cells by carbon-ion implantation of tri-layer titania film electrodes
Abstract:TiO2tri-layer structure films were modified by C-ions implantation for improving the photovoltaic performance of dye-sensitized solar cells(DSSCs), in which the structure of TiO2 changes from rutile to anatase and the sizes of TiO2 particles increase. The optimal concentration of ions implantation for C-implanted cells is 19 1015 atom cm-2,and the maximum conversion efficiency of 5.32 % is achieved(luminous intensity of 1 sun, light irradiance of AM1.5G),which is 25.2 % higher than that of unimplanted cell. The significant improvement in conversion efficiency by carbonion implantation is contributed to reducing charge recombination and enhancing the light-harvesting ability, as indicated from incident photon-to-collected electron conversion efficiency(IPCE) and ultraviolet-visible(UV-Vis) measurements. Furthermore, the charge carrier's lifetime in the trilayer titania films is prolonged after carbon-ion implantations.
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