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A review of advanced proton-conducting materials for hydrogen separation
Affiliation:1. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, Jiangsu, China;2. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China;3. Department of Chemical & Biochemical Engineering, University of British Columbia, Vancouver, BC V6T 1W5, Canada;4. Department of Chemical Engineering, University of Missouri–Columbia, Columbia 65211, USA;1. Center of Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191, People''s Republic of China;2. School of Materials Engineering, YanCheng Institute of Technology, YanCheng 224051, People''s Republic of China;1. School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, China;2. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng 224051, China;1. School of Materials Engineering, YanCheng Institute of Technology, YanCheng 224051, People''s Republic of China;2. Center of Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191, People''s Republic of China;1. School of Materials Engineering, Yancheng Institute of Technology, Yancheng, 224051, PR China;2. Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, PR China;3. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, 224051, PR China;4. School of Chemistry & Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224051, PR China;1. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, China;2. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China;3. Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing 210009, China;4. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;1. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, China;2. School of Materials Engineering, Yancheng Institute of Technology, Yancheng 224051, China;3. College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China;4. School of Automotive Engineering, Yancheng Institute of Technology, Yancheng 224051, China
Abstract:This paper provides a comprehensive overview of developments and recent trends in H2 separation technology that uses dense proton–electron conducting ceramic materials and their associated membranes. Various proton–electron conducting materials and their associated membranes are summarized and classified into several important categories, such as Ni-composite proton-conducting materials, as well as tungstate-based, BaPrO3-based, LaGaO3-based, and niobate/tantalite composite metal oxide-based ceramic materials/membranes. Various membrane designs, including asymmetric ceramic membranes (supported and self-supported) and surface-modified membranes, are also reviewed. Several important properties of ceramic materials and membranes, such as proton and electron conductivity and performance (i.e., H2 transport flux and lifetime stability), are also discussed. To highlight the technical progress in this area, all possible ceramic materials and associated membranes are summarized, along with their properties and performance, to help readers quickly locate the information they are looking for. Based on this review, several challenges hindering the maturation of this technology are analyzed in depth, and possible research directions for overcoming these challenges are suggested.
Keywords:Hydrogen separation  Proton and electron conduction  Ceramic materials and membranes
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