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对叔丁基酚改性环氧酚醛涂料的合成与表征
引用本文:孙明超,徐日炜,胡向蔚,余鼎声.对叔丁基酚改性环氧酚醛涂料的合成与表征[J].涂料工业,2006,36(2):52-54.
作者姓名:孙明超  徐日炜  胡向蔚  余鼎声
作者单位:1. 北京化工大学材料科学与工程学院,100029
2. 中国食品发酵工业研究院,北京,100027
摘    要:以对叔丁基酚、苯酚、甲醛水溶液为原料,在氨水的催化下,合成了一种对叔丁基酚改性的甲阶酚醛树脂。考察了对叔丁基酚含量对固含量和涂料性能的影响。利用红外光谱、DSC和GPC方法分析了产物的结构,并与环氧树脂混合配制出一种性能优异的非双酚A型食品罐用环氧酚醛涂料。

关 键 词:对叔丁基酚  环氧酚醛涂料  食品罐  红外光谱  凝胶渗透色谱
文章编号:0253-4312(2006)02-0052-03
收稿时间:2005-08-08
修稿时间:2005-08-08

Synthesis and Characterization of Para-Tertiary Butyl Phenol Modified Epoxy Phenolic Coatings
Sun Mingchao,Xu Riwei,Hu Xiangwei.Synthesis and Characterization of Para-Tertiary Butyl Phenol Modified Epoxy Phenolic Coatings[J].Paint & Coatings Industry,2006,36(2):52-54.
Authors:Sun Mingchao  Xu Riwei  Hu Xiangwei
Abstract:A para-tertiary butyl phenol modified resol has been prepared by using para-tertiary butyl phenol,phenol and formaldehyde solution as raw materials at the presence of ammonia water as catalyst,which is blended with epoxy resin forming a excellent non bisphenol A type epoxy phenolic coatings for food cans.The influence of content of para-tertiary butyl phenol on solid and performance of coatings is investigated.The structure of resol is characterized by use of DSC and GPC.
Keywords:para-tertiary butyl phenol  epoxy phenolic resin coatings  can  IR  GPC
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