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真空钎焊金刚石界面碳化物的形貌
引用本文:卢金斌,徐九华. 真空钎焊金刚石界面碳化物的形貌[J]. 中国有色金属学报, 2007, 17(7): 1143-1148
作者姓名:卢金斌  徐九华
作者单位:1. 中原工学院,材料与化学工程学院,郑州,450007;南京航空航天大学,机电学院,南京,210016
2. 南京航空航天大学,机电学院,南京,210016
基金项目:国家自然科学基金;江苏省自然科学基金
摘    要:采用Ni-Cr、Ag-Cu-Ti和Ti-Zr-Ni-Cu等钎料分别对单晶金刚石与基体进行真空钎焊。SEM、EDS和XRD等分析结果表明,在一定的钎焊温度、时间及真空度下,金刚石与所有钎料均形成化学冶金结合,在不同钎料界面形成的碳化物的种类、数量和形貌分布却显著不同;Ni-Cr合金钎料在界面处形成片状的Cr3C2和针状Cr7C3;Ag-Cu-Ti钎料则生成不连续分布块状TiC,Ti-Zr-Ni-Cu生成的是呈鹅卵石状连续分布的TiC。

关 键 词:金刚石  碳化物  真空钎焊  钎料
文章编号:1004-0609(2007)07-1143-06
收稿时间:2006-07-18
修稿时间:2007-05-29

Morphology of carbide on diamond interface by vacuum brazing
LU Jin-bin,XU Jiu-hua. Morphology of carbide on diamond interface by vacuum brazing[J]. The Chinese Journal of Nonferrous Metals, 2007, 17(7): 1143-1148
Authors:LU Jin-bin  XU Jiu-hua
Affiliation:1. School of Materials and Chemical Engineering, Zhongyuan University of Technology, Zhcngzhou 450007, China; 2. College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
Abstract:Using Ni-Cr, Ag-Cu-Ti, and Ti-Zr-Ni-Cu alloy as fillers diamond was brazed on matrix in vacuum furnace. By SEM, EDX and XRD analysis, it is shown that at certain brazing temperature, duration and vacuum level, chemical bonding takes place on the interface between the diamond and all the fillers. The kind, amount, morphology and distribution of carbides formed are different on different filler interface. Some slice-like Cr3C2 and acicular Cr7C3 carbides exist on the interface of Ni-Cr, discontinuous-lump-like TiC carbide exists on the interface of Ag-Cu-Ti, and continuous-cobble-like TiC exists on the interface of Ti-Zr-Ni-Cu.
Keywords:diamond   carbide   vacuum brazing   filler
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