首页 | 本学科首页   官方微博 | 高级检索  
     

化学反应体系中温度场自组织类型和产生阈值的多样性研究
引用本文:韩玉民,栗志,罗久里. 化学反应体系中温度场自组织类型和产生阈值的多样性研究[J]. 化工学报, 2007, 58(12): 2975-2979
作者姓名:韩玉民  栗志  罗久里
作者单位:四川大学化学学院化学物理研究所,四川 成都 610064
基金项目:教育部高等学校博士学科点专项科研基金
摘    要:选择和控制反应过程的温度是反应器设计和控制中的重要问题。线性稳定性分析说明,在Lindemann单分子化学反应-扩散-热传导体系中,由于非线性动力学方程组具有诸多控制参数,导致温度场自组织类型及其产生阈值的多样性。数值模拟结果还说明,Turing分支因其产生阈值的不同,致使温度场空间周期结构的波数出现了多值性。毫无疑问,这些重要结果是实施化学反应器的合理设计选型及最佳控制所必须考虑的内容。

关 键 词:化学反应-扩散-热传导  温度场自组织  Lindemann模型  化学反应器设计与控制  
收稿时间:2007-05-08
修稿时间:2007-7-17 

Diversity of temperature field self-organization structures and occurring critical values in chemical reaction systems
HAN Yumin,LI Zhi,LUO Jiuli. Diversity of temperature field self-organization structures and occurring critical values in chemical reaction systems[J]. Journal of Chemical Industry and Engineering(China), 2007, 58(12): 2975-2979
Authors:HAN Yumin  LI Zhi  LUO Jiuli
Abstract:It is very important for reactor design and control to choose and control the temperature throughout the reaction process.The linear stability analysis showed that control parameters contained in a nonlinear kinetic system of equations resulted in the diversity of temperature self-organization structures and occurring critical values in Lindemann uni-molecular chemical reaction-diffusion-heat conduction systems.The results of numerical simulations also showed that the differences of occurring critical values of Turing bifurcation led to multiple wave number values of spatially periodic structures of temperature field.Without doubt,these significant results should be considered in order to reasonably design,correctly choose the reactor type and optimally control chemical reactors.
Keywords:chemical reaction-diffusion-heat conduction  self-organization of temperature field  Lindemann model  design and control of chemical reactor
本文献已被 CNKI 维普 万方数据 等数据库收录!
点击此处可从《化工学报》浏览原始摘要信息
点击此处可从《化工学报》下载全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号