Introduction of silica into thermo-responsive poly(N-isopropyl acrylamide) hydrogels: A novel approach to improve response rates |
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Authors: | Kurt Van Durme Wouter Loos |
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Affiliation: | a Department of Physical Chemistry and Polymer Science—FYSC (TW), Vrije Universiteit Brussel (VUB), Pleinlaan 2, B-1050 Brussels, Belgium b Polymer Chemistry Division, Department of Organic Chemistry, Ghent University (UGent), Krijgslaan 281 S4, B-9000 Ghent, Belgium |
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Abstract: | The response rates of novel thermo-responsive poly(N-isopropyl acrylamide) (PNIPAM) hybrid hydrogels are compared to those of conventional chemically crosslinked PNIPAM hydrogels. The former materials were obtained by applying the sol-gel technology, in which the inorganic silica particles act as physical crosslinks for the organic polymer chains, leading to a semi-interpenetrating polymer network structure. In situ modulated temperature DSC shows that the introduction of hydrophilic silica improves the thermal response rate of the hybrid hydrogels to a great extent as compared to aqueous PNIPAM solutions and conventional PNIPAM hydrogels. Ex situ gravimetrical measurements also illustrate that the shrinking/swelling rate of the hybrid hydrogels is largely improved. It is assumed that the uniform distribution of the SiO2 units, as demonstrated by cryo-field emission scanning electron microscopy, causes the silica to act as nano-sized water reservoirs, which reduce the characteristic diffusion length of water in the PNIPAM matrix so that it can be transported faster within the hybrid PNIPAM nano-composite. |
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Keywords: | Hydrogels Poly(N-isopropyl acrylamide) Phase separation kinetics |
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