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ZnO纳米棒的低温生长及光致发光性能
引用本文:郎集会,杨景海,李长生,韩强,杨丽丽,王丹丹,高铭,刘晓艳.ZnO纳米棒的低温生长及光致发光性能[J].半导体学报,2008,29(11):2260-2264.
作者姓名:郎集会  杨景海  李长生  韩强  杨丽丽  王丹丹  高铭  刘晓艳
作者单位:江苏大学材料科学与工程学院,镇江,212013;吉林师范大学凝聚态物理研究所,四平,136000;江苏大学材料科学与工程学院,镇江,212013;吉林师范大学凝聚态物理研究所,四平,136000;中国科学院长春光学精密机械与物理研究所,长春,130033;中国科学院研究生院,北京,100049
摘    要:采用化学溶液沉积法在ITO导电玻璃上制备近一维ZnO纳米棒. 利用X射线衍射(XRD) 、扫描电子显微镜(SEM)和光致发光谱(PL)对样品进行表征,研究了不同Zn2+摩尔浓度和不同生长时间对样品的结构、形貌和光致发光性能的影响. 结果表明,所制备的ZnO纳米棒为纤锌矿结构并沿c轴择优取向生长. 另外,随着Zn2+摩尔浓度的增加,纳米棒的直径增大. 当Zn2+摩尔浓度为0.1M时,ZnO纳米棒的直径和长度都随生长时间的增加而增加. PL测试表明,样品均具有良好的发光性能,并且ZnO纳米棒的结晶质量随着Zn2+摩尔浓度和生长时间的增加均有所提高.

关 键 词:ZnO纳米棒  Zn2+摩尔浓度  生长时间  光致发光
收稿时间:4/7/2008 10:55:49 PM
修稿时间:6/20/2008 9:42:13 AM

Photoluminescence Properties of ZnO Nanorods Prepared Under Low Temperature
Lang Jihui,Yang Jinghai,Li Changsheng,Han Qiang,Yang Lili,Wang Dandan,Gao Ming and Liu Xiaoyan.Photoluminescence Properties of ZnO Nanorods Prepared Under Low Temperature[J].Chinese Journal of Semiconductors,2008,29(11):2260-2264.
Authors:Lang Jihui  Yang Jinghai  Li Changsheng  Han Qiang  Yang Lili  Wang Dandan  Gao Ming and Liu Xiaoyan
Affiliation:School of Material Science and Engineering,Jiangsu University,Zhenjiang 212013,China;Institute of Condensed State Physics,Jilin Normal University,Siping 136000,China;School of Material Science and Engineering,Jiangsu University,Zhenjiang 212013,China;Institute of Condensed State Physics,Jilin Normal University,Siping 136000,China;School of Material Science and Engineering,Jiangsu University,Zhenjiang 212013,China;Institute of Condensed State Physics,Jilin Normal University,Siping 136000,China;Institute of Condensed State Physics,Jilin Normal University,Siping 136000,China;Key Laboratory of Excited State Processes,Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,Changchun 130033,China ;Graduate University of the Chinese Academy of Sciences,Beijing 100049,China;Institute of Condensed State Physics,Jilin Normal University,Siping 136000,China;Institute of Condensed State Physics,Jilin Normal University,Siping 136000,China
Abstract:Zinc oxide (ZnO) nanorods are grown on ITO conducting glass with the chemical bath deposition (CBD) method.XRD,SEM,and PL are used to characterize the crystal structures,surface morphologies,and photoluminescence properties of ZnO nanorods.The X-ray measurement results show that the growth orientation of the as-prepared ZnO nanorods is (002).The SEM results show that the size of ZnO nanorods increases with the molar concentration of zinc nitrate,and the diameter and length of nanorods increases significantly through tuning the reaction time when the molar concentration is 0.1M.The photoluminescence measurements show that the all the samples have good photoluminescence behaviors.The crystallization of the samples increases with the molar concentration of zinc nitrate and the reaction time.
Keywords:ZnO nanorod  molar concentration of zinc nitrate  reaction time  photoluminescence
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