A method of investigating the kinetics of high-temperature ductility variation of porous solids during sintering under pressure

Conclusions A method is proposed making it possible to study the high-temperature kinetics of the variation of the coefficients of shear ductility of a porous solid and its material during sintering under pressure. An investigation was carried out into the variation of the ductility of copper powder compacts in the temperature range 700–950°C. Experimental data are compared with results obtained on the basis of the theory of diffusion-viscous flow and a general rheological theory of sintering. It has been established that in the initial stage of sintering at 950°C the coefficient of shear ductility of copper increases linearly with time. Under conditions of diffusion-viscous flow of a polycrystalline material, this is due to diffusional grain growth according to a parabolic law. It is shown that experimental values of shear ductility of copper are smaller than values obtained on the basis of the rheological theory of sintering. Values approximating most closely to experimental data have been obtained with a model of an ideal porous solid.Translated from Poroshkovaya Metallurgiya, No. 11(299), pp. 11–17, November, 1987.