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SnS2/TiO2 nanocomposites with enhanced visible light-driven photoreduction of aqueous Cr(VI)
Affiliation:1. Key Laboratory of Photochemical Biomaterials and Energy Storage Materials of Heilongjiang Province, College of Chemistry and Chemical Engineering; Key Lab for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin 150025, PR China;2. Thermo Fisher Scientific (China), Bioisland, Haizhu district, Guangzhou 510000, China;1. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China;2. Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China;3. Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China;1. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China;2. School of Materials Science and Engineering, Guangxi University, Nanning 530004, China;1. School of Chemistry and Chemical Engineering, Institute of Physical Chemistry, Development Center for New Materials Engineering & Technology in Universities of Guangdong, Lingnan Normal University, Zhanjiang 524048, PR China;1. College of Chemistry, Jilin University, Changchun, 130012, PR China;2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, PR China;1. School of Chemical Engineering, Northwest University, No. 229 Taibai North Road, Xi’an 710069, China;2. School of Physics, Northwest University, No. 229 Taibai North Road, Xi’an 710069, China;3. Institute of Modern Physics, Northwest University, Xi’an 710069, China
Abstract:SnS2/TiO2 nanocomposites have been synthesized via microwave assisted hydrothermal treatment of tetrabutyl titanate in the presence of SnS2 nanoplates in the solvent of ethanol at 160 °C for 1 h. The physical and chemical properties of SnS2/TiO2 were studied by XRD, FESEM, EDS, TEM, XPS and UV–vis diffuse reflectance spectra (DRS). The photocatalytic activity of SnS2/TiO2 nanocomposites were evaluated by photoreduction of aqueous Cr(VI) under visible light (λ>420 nm) irradiation. The experimental results showed that the SnS2/TiO2 nanocomposites exhibited excellent reduction efficiency of Cr(VI) (~87%) than that of pure TiO2 and SnS2. The SnS2/TiO2 nanocomposites were expected to be a promising candidate as effective photocatalysts in the treatment of Cr(VI) wastewater.
Keywords:Nanocomposites  Cr(VI)  Visible photoreduction  Crystal structure
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