Effect of CuO addition on magnetic and electrical properties of Sr2Bi4Ti5O18 lead-free ferroelectric ceramics |
| |
| Affiliation: | 1. Key Laboratory of Solidification Control and Digital Preparation Technology (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, PR China;2. School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, PR China;1. Micro-optoelectronic Systems Laboratories, Xi’an Technological University, Xi’an 710032, Shaanxi, China;2. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, School of Electronic Science and Engineering, Xi’an Jiaotong University, Xi''an, 710049, China;1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China;2. School of Physics and Electronics, Henan University, Kaifeng, 475004, China;3. International School of Material Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China;1. College of Science, Civil Aviation University of China, Tianjin 300300, China;2. School of Electronics and Information Engineering, Tianjin Polytechnics University, Tianjin 300160, China |
| |
| Abstract: | The effect of CuO addition on magnetic and electrical properties of Sr2Bi4Ti5O18 (SBT) lead-free bismuth layered structure ferroelectric ceramics have been studied and reported. Interestingly, the prepared samples exhibit multiferroic behavior with the coexistence of magnetic and ferroelectric phase transition temperature. Magnetic phase transition with Neel?s temperature (TN) of 657 K is observed at 0.75 mol% of CuO added SBT ceramics, which is higher than the well known multiferroic BiFeO3 (643 K) and the ferroelectric phase transition with Curie temperature (TC) of 587 K is observed at 1 mol% of CuO added SBT ceramics, which is relatively higher than the reported pure SBT ceramics (558 K). Further, the electrical properties such as dielectric, ferroelectric, piezoelectric, leakage current density characteristics and optical properties were investigated as a function of x (x=0, 0.25, 0.5, 0.75 and 1 mol%). Presence of strong magnetic super-exchange interactions in CuO and the creation of oxygen vacancies play a vital role in the enhancement of magnetic and electrical properties of CuO doped SBT ceramics. Moreover, the present results indicate that, small amount (0.25 mol%) of CuO addition in SBT ceramics enhances the electrical properties significantly and vice versa, large amount (0.75 mol%) of CuO addition enhances the magnetic properties. Thus, the presence of magneto-electric coupling effect was observed in CuO doped Sr2Bi4Ti5O18 ferroelectric ceramics. |
| |
| Keywords: | Multiferroics Neel?s temperature Curie temperature Leakage current density Optical band gap |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
