A hydration study of various calcium sulfoaluminate cements |
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Affiliation: | 1. Department of Civil and Environmental Engineering, University of California, Berkeley, CA, USA;2. School of Engineering, University of Basilicata, Potenza, Italy;1. CEA, DEN, DTCD, SPDE, F-30207 Bagnols-sur-Cèze cedex, France;2. LMCPA, Université de Valenciennes et du Hainaut Cambrésis, 59600 Maubeuge, France;3. Ecole des Mines de Douai, LGCgE-GCE, 59508 Douai, France |
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Abstract: | The present work studies the hydration process and microstructural features of five calcium sulfoaluminate (CSA) cements and a ternary mixture including also ordinary Portland cement (OPC). The pastes were studied with simultaneous differential thermal-thermogravimetric (DTA-TG) analysis, mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and expansion/shrinkage tests. The DTA-TG analysis confirmed the role of the hydration reactions involving the main CSA clinker constituent, tetracalcium trialuminate sulfate, which produced (i) ettringite when combined with lime and calcium sulfate, (ii) ettringite and aluminum hydroxide in the presence of calcium sulfate alone, and (iii) monosulfate and aluminum hydroxide in the absence of both lime and calcium sulfate. The MIP and SEM were able to discriminate between expansive (ternary mixture and CSA cement containing 50% gypsum) and non-expansive cements. Expansive cement pastes had (i) a nearly unimodal pore size distribution shifted toward higher radii and (ii) ettringite crystals smaller in size during the first day of curing. In a SEM image of a hardened paste of the CSA cement containing 50% gypsum, a stellate ettringite cluster was observed. |
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Keywords: | Cement Ettringite Hydration Expansion Gypsum Sulfoaluminate |
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