Graphene-gold nanostructure composites fabricated by electrodeposition and their electrocatalytic activity toward the oxygen reduction and glucose oxidation |
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Authors: | Yaojuan Hu Chenxin Cai |
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Affiliation: | Jiangsu Key Laboratory of New Power Batteries, Jiangsu Key Laboratory of Biofunctional Materials, Laboratory of Electrochemistry, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, PR China |
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Abstract: | A gold nanoparticles (Au NPs)-graphene nanocomposite (Au-graphene nanocomposite) was prepared by electrochemically depositing Au NPs on the surface of graphene sheets, and characterized by scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), and electrochemical methods. The morphology and size of the Au NPs could be easily controlled by adjusting the electrodeposition time and the concentration of precursor (AuCl4−). The electrocatalytic activities of the nanocomposites toward oxygen reduction and glucose oxidation were investigated by cyclic voltammetry. The results indicated that the nanocomposites had a higher catalytic activity than the Au NPs or graphene alone, indicating the synergistic effect of graphene and Au NPs. Therefore, this study has provided a general route for fabrication of graphene-based noble metal nanomaterials composite, which could be potential utility to fuel cells and bioelectroanalytical chemistry. |
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Keywords: | Electrocatalysis Carbon materials Gold nanostructures Oxygen reduction Glucose oxidation |
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