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Facile Hydrogen Evolution Reaction on WO3 Nanorods
Authors:Janarthanan Rajeswari  Pilli Satyananda Kishore  Balasubramanian Viswanathan  Thirukkallam Kanthadai Varadarajan
Affiliation:(1) Department of Chemistry, National Centre for Catalysis Research, Indian Institute of Technology Madras, Chennai, 600 036, India
Abstract:Tungsten trioxide nanorods have been generated by the thermal decomposition (450 °C) of tetrabutylammonium decatungstate. The synthesized tungsten trioxide (WO3) nanorods have been characterized by XRD, Raman, SEM, TEM, HRTEM and cyclic voltammetry. High resolution transmission electron microscopy and X-ray diffraction analysis showed that the synthesized WO3 nanorods are crystalline in nature with monoclinic structure. The electrochemical experiments showed that they constitute a better electrocatalytic system for hydrogen evolution reaction in acid medium compared to their bulk counterpart.
Keywords:Tungsten trioxides  Thermal decomposition  Nanorods  Hydrogen evolution reaction  Electrocatalyst
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