Abstract: | Allyloxyethyl 2-cyanoacrylate monomer was synthesized and characterized for the first time. It was found that this monomer retains the typical properties of cyanoacrylate adhesives such as fast setting time at room temperature, adhesion to most materials, and high strength of bonded joints. Because of its long ester group and the reactive allyl group, this cyanoacrylate monomer produces adhesive bonds which have improved elasticity and heat resistance. IR and DSC studies showed crosslinking of the adhesive layer when subjected to elevated temperature, which explains the increased tensile shear strength of steel bonded joints. It was found that allyloxyethyl 2-cyanoacrylate can also be used as a crosslinking component for cyanoacrylate adhesives, based on ethyl 2-cyanoacrylate. Less than 10% of allyloxyethyl 2-cyanoacrylate in the mixture is needed for increasing, over three times, the tensile shear strength of the adhesive joint after ageing at 100°C. |