Adhesion between rubber compounds and ternary-alloy-coated steel cords,Part I: effect of cobalt plating amount in ternary-alloy-coated steel cords

The adhesion between a rubber compound and ternary-alloy-coated steel cords with different cobalt plating amounts (0, 2 and 4 wt%) was investigated to understand the role of cobalt in stabilizing adhesion to the rubber compound. The adhesion property of ternary alloy coated steel cords to the rubber compound did show significant enhancement after cure for the ternary alloy coated steel cord with 2 wt% cobalt plating. Further increase of cobalt plating in ternary-alloy-coated steel cord was responsible for the poor adhesion to the rubber compound. An improvement in adhesion durability after aging in various hostile environments was shown for the ternary-alloy-coated steel cord with 2 wt% cobalt plating. The interphase between the ternary-alloy-coated steel cords and the rubber compound studied using AES showed a stable adhesion interphase by optimum cobalt plating, resulting in enhancement of adhesion retention.