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Growth and Characterization of Unintentionally Doped GaSb Nanowires
Authors:Robert A Burke  Xiaojun Weng  Meng-Wei Kuo  Young-Wook Song  Anne M Itsuno  Theresa S Mayer  Steven M Durbin  Roger J Reeves  Joan M Redwing
Affiliation:(1) Harvard University, Cambridge, MA 02138, USA;(2) Ben Gurion University, Beer Sheva, Israel;(3) Present address: University of Houston, Houston, TX 77004, USA
Abstract:GaSb nanowires were synthesized on c-plane sapphire substrates by gold-mediated vapor–liquid–solid (VLS) growth using a metalorganic chemical vapor deposition process. A narrow process window for GaSb nanowire growth was identified. Chemical analysis revealed variations in the catalyst composition which were explained in terms of the Au-Ga-Sb ternary phase diagram and suggest that the VLS growth mechanism was responsible for the nanowire growth. The nominally undoped GaSb nanowires were determined to be p-type with resistivity on the order of 0.23 Ω cm. The photoluminescence was found to be highly dependent on the V/III ratio, with an optimal ratio of unity.
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