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双波长K系数法同时测定重油中的钴镍
引用本文:刘立行,王启丰.双波长K系数法同时测定重油中的钴镍[J].石油化工,1996(7).
作者姓名:刘立行  王启丰
作者单位:抚顺石油学院应用化学系(刘立行),新疆塔里木农垦大学基础课部(王启丰)
摘    要:采用M2+-OP-5-Br-PADAP显色体系,测定波长对为560.0/587.0nm。考查了正三辛胺萃取分离干扰离子的条件,用双波长K系数法同时测定了合成样及重油样中的钴镍,合成样的回收率为94.6%—105.4%,重油样的测定结果与标准加入法结果一致

关 键 词:双波长K系数法  钴镍  重油

Simultaneous Determination of Cobalt,Nickel in Heavy Oil by Double Wavelength K Coefficient Spectrophotometry
Liu,Lihang.Simultaneous Determination of Cobalt,Nickel in Heavy Oil by Double Wavelength K Coefficient Spectrophotometry[J].Petrochemical Technology,1996(7).
Authors:Liu  Lihang
Abstract:M(Ⅱ) OP 5 Br PADAP coloured system and a wavelength pair of 560.0/587.0 nm are used for determining cobalt and nickel.The conditions for the extractive separation of interfering ions are investigated.Double wavelength K coefficient method is applied to determining cobalt and nickel in synthetic samples and heavy oil samples.The recovery rate for the synthetic samples is 94 6% 105 4% and the results for the heavy oil samples agree with that of the standard addition method.
Keywords:ouble  wavelength    K    coefficient  method  cobalt  nickel  heavy  Oil
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