| 分子筛对丙烷和丙烯的吸附脱附性能 |
| |
| 引用本文： | 耿尧,张建霞,张明恂,刘立成,訾学红,何洪.分子筛对丙烷和丙烯的吸附脱附性能[J].工业催化,2010,18(9):64-69. |
| |
| 作者姓名： | 耿尧 张建霞 张明恂 刘立成 訾学红 何洪 |
| |
| 作者单位： | 北京工业大学环境与能源工程学院化学化工系，北京 100124 |
| |
| 基金项目： | 国家自然科学基金，国家自然科学基金重点项目，国家高技术研究发展计划(863计划) |
| |
| 摘 要： | 碳氢化合物(HC)捕获器是解决汽车冷启动问题的有效途径,分子筛作为碳氢化合物捕获剂的应用越来越受到重视。以丙烷和丙烯混合气为探针分子,利用瞬态应答(TSR)和程序升温脱附(TPD)技术,对4种类型分子筛的HC吸附脱附能力进行研究。结果表明,β-2分子筛的丙烷和丙烯脱附温度较高,分别为422℃和450℃,吸附量3.24 mL·g~(-1),ZSM-5-3分子筛的丙烷和丙烯脱附温度为130℃和127℃,碳氢化合物吸附量为7.87 mL·g~(-1)。
|
| 关 键 词： | 催化化学 碳氢化合物捕获剂 分子筛 瞬态应答 程序升温脱附 |
Absorption and desorption ability of propane and propylene on zeolites |
| |
| GENG Yao,ZHANG Jianxia,ZHANG Mingxun,LIU Licheng,ZI Xuehong,HE Hong.Absorption and desorption ability of propane and propylene on zeolites[J].Industrial Catalysis,2010,18(9):64-69. |
| |
| Authors: | GENG Yao ZHANG Jianxia ZHANG Mingxun LIU Licheng ZI Xuehong HE Hong |
| |
| Affiliation: | Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China |
| |
| Abstract: | Zeolites used as hydrocarbon adsorbents are paid more and more attention. Admixture of propane and propylene were used as probe molecules for HC. Adsorption and desorption behaviors of HC on four types of zeolites were studied using transient switch response （TSR） and temperature program desorption （TPD）. The experimental results demonstrated that β-2 zeolite had the highest desorption temperature of propane （422 ℃ ） and propylene （450℃ ）,and adsorption amount of hydrocarbon was 3.24 mL·g^-1 desorption temperature of propane and propylene over ZSM-5-3 zeolite was 130 ℃ and 127℃, respectively and adsorption amount of hydrocarbon was 7.87 mL·g^-1 |
| |
| Keywords: | catalytic chemistry hydrocarbon adsorbent zeolite transient switch resnonse （ TSR ） TPD |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《工业催化》浏览原始摘要信息 |
|
点击此处可从《工业催化》下载全文 |
|
