Syntheses and polymerizations of macromers |
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Authors: | Ryuzo Asami Mikio Takaki Kazuo Kita Eiji Asakura |
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Affiliation: | (1) Department of Synthetic Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466 Nagoya, Japan |
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Abstract: | Summary Living poly(tetrahydrofuran) (PTHF) was coupled with sodium p-vinylbenzyloxide quantitatively to prepare a macromer of p-vinylbenzyloxyl poly(tetrahydrofuran) (VBO-PTHF). The radical polymerization of the macromer with AIBN was performed. From the GPC measurement the conversion of the macromer to poly-macromer was shown to be high percentage, but the degree of polymerization of poly-macromer was much lower than that expected in the case of regular monomers such as styrene. |
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