首页 | 本学科首页   官方微博 | 高级检索  
     


Platinum‐Catalyzed Divergent Reactivity of α‐Hydroxyallenes: Synthesis of Dihydrofurans and α,β‐Unsaturated Ketones
Authors:Benito Alcaide  Pedro Almendros  Israel Fernndez  Teresa Martínez del Campo  Teresa Naranjo
Abstract:α‐Allenols were catalytically transformed into dihydrofurans in the presence of platinum dichloride. Notably, using platinum dichloride along with silver triflate as the catalytic system, α,β‐unsaturated ketones were obtained. Therefore, the role of the silver salt may not just consist in the activation of the platinum precatalyst.
image

Keywords:allenes  heterocycles  homogeneous catalysis  platinum  regioselectivity
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号