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EVA/Al_2O_3纳米复合材料的结构与性能
引用本文:孙国恩,张莉,李红姬,张春玲,梁继才,张万喜. EVA/Al_2O_3纳米复合材料的结构与性能[J]. 吉林大学学报(工学版), 2005, 35(6): 577-581
作者姓名:孙国恩  张莉  李红姬  张春玲  梁继才  张万喜
作者单位:吉林大学材料科学与工程学院,长春,130022
基金项目:“863”国家高技术研究发展计划项目(2003AA302310).
摘    要:以纳米A l2O3为增强材料,制备了EVA/A l2O3纳米复合材料,并采用FESEM、FT-NIR、SEM等测试手段表征纳米A l2O3微粒在EVA基体中的分散性与结构,研究了纳米A l2O3的质量分数对纳米复合材料力学性能的影响。结果表明:A l2O3微粒以20 nm左右的粒径分散于EVA基体中,并与EVA形成化学键合结构,复合材料的断裂机理发生变化。填充质量分数为0.5%的纳米A l2O3微粒时,拉伸强度提高13.0%;当加入的纳米A l2O3的质量分数为1%时,断裂伸长率可提高13.3%。

关 键 词:材料表面与界面  纳米复合材料  熔融共混  表面改性  EVA  纳米Al2O3
文章编号:1671-5497(2005)06-0577-05
收稿时间:2005-04-04
修稿时间:2005-04-04

Structure and Properties of EVA/Al2O3 Nano-composite Materials
SUN Guo-en,ZHANG Li,LI Hong-ji,ZHANG Chun-ling,LIANG Ji-cai,ZHANG Wan-xi. Structure and Properties of EVA/Al2O3 Nano-composite Materials[J]. Journal of Jilin University:Eng and Technol Ed, 2005, 35(6): 577-581
Authors:SUN Guo-en  ZHANG Li  LI Hong-ji  ZHANG Chun-ling  LIANG Ji-cai  ZHANG Wan-xi
Affiliation:College of Materials Science and Engineering, Jilin University, Changchun 130022, China
Abstract:Nanocomposite was prepared by nano-Al_2O_3 and ethylene-vinyl acetate(EVA) resin.The dispersibility and structure of nano-Al_2O_3 in EVA matrix were characterized by FESEM,FT-NIR and SEM.The effects of the content of nano-Al_2O_3 on the mechanical properties of the nanocomposite were studied.Experimental results show that nano-Al_2O_3 particles with size of about 20 nm are dispersed in EVA matrix,linked with EVA through chemical bond,and the fracture machanism changed correspordingly.With 0.5% Al_2O_3 addition,the ultimate tensile strength is improved by 13.0%;with 1.0% Al_2O_3 addition,the fracture elongation is increased by 13.3%.
Keywords:materials surface and interface   nano-composite materials   melt blend   surface modification  EVA    nano-A12O3
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