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Synthesis and characterization of acrylate–oxetane interpenetrating polymer networks through a thermal-UV dual cure process
Authors:M. Sangermano  G. Malucelli  A. Priola  M. Manea
Affiliation:1. Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Unità Locale INSTM, C.so Duca degli Abruzzi 24, 10129 Torino, Italy;2. Perstorp Specialty Chemicals, 284 80 Perstorp, Sweden
Abstract:In the present work, a thermal-UV dual-cure process was performed on acrylate–oxetane systems. A 1:1 molar mixture of difunctional acrylate–oxetane mixture was prepared starting from 2,2-Bis(4-(3-acryloxy-2-hydroxypropoxy)phenyl)propane (BPADA) and 3-ethyl-3-{[(3-ethyloxetan-3-yl)methoxy]methyl}oxetane (OXT-221, DOX). Following a difunctional oxetane-acrylic monomer (OXAC) was synthesized.
Keywords:IPN's   Thermal&ndash  UV dual cure process   Acrylic monomers   Oxetane monomers
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