| 对二甲氨基苯基五唑和对羟基苯基五唑的低温合成与NMR表征 |
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| 引用本文： | 徐敏,毕福强,张皋,王民昌,葛忠学,陈智群,许诚.对二甲氨基苯基五唑和对羟基苯基五唑的低温合成与NMR表征[J].含能材料,2012,20(5):596-600. |
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| 作者姓名： | 徐敏 毕福强 张皋 王民昌 葛忠学 陈智群 许诚 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 摘 要： | 分别以对二甲氨基苯胺和对羟基苯胺为原料,在-40℃条件下合成出对二甲氨基苯基五唑(p-DMAPP)和对羟基苯基五唑(p-HPP)。用低温1HNMR、13CNMR、1H-13CHMBC、15NNMR和1H-15NHMBC表征了它们的结构。结果表明,其氢谱和碳谱数据与文献值一致。五唑的N信号分别被指配为:p-DMAPP,N-1(δN-80.0),N-2/5(δN-27.3),N-3/4(δN5.1);对p-HPP,N-1(δN-84.1),N-2/5(δN-28.1),N-3/4(δN4.2)。
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| 关 键 词： | 有机化学 对二甲胺基苯基五唑 对羟基苯基五唑 合成 核磁共振 |
| 收稿时间： | 2011/12/8 0:00:00 |
| 修稿时间： | 4/1/2012 12:00:00 AM |
Synthesis and NMR Characterization of p-Dimethylaminophenylpentazole and p-Hydroxyphenylpentazole at Low Temperature |
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| XU Min
,
BI Fu-qiang
,
ZHANG Gao
,
WANG Min-chang
,
GE Zhong-xue
,
CHEN Zhi-qun
,
XU Cheng.Synthesis and NMR Characterization of p-Dimethylaminophenylpentazole and p-Hydroxyphenylpentazole at Low Temperature[J].Chinese Journal of Energetic Materials,2012,20(5):596-600. |
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| Authors: | XU Min BI Fu-qiang ZHANG Gao WANG Min-chang GE Zhong-xue CHEN Zhi-qun XU Cheng |
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| Affiliation: | (Xi′an Modern Chemistry Research Institute, Xi′an 710065, China) |
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| Abstract: | p-Dimethylaminophenylpentazole(p-DMAPP) and p-hydroxyphenylpentazole(p-HPP) were synthesized at -40 ℃, using N1,N1-dimethylbenzene-1,4-diamine and 4-aminophenol as starting meaterials, respectively. Their stuctures were characterized by 1H NMR, 13C NMR , 1H-13C HMBC, 15N NMR and 1H-15N HMBC at low temperature. The results show that the 1H NMR and 13C NMR data of p-DMAPP and p-HPP are in accordant with the literature values. Nitrogen signals of pentazole are assigned as N-1(δN -80.0), N-2/5(δN -27.3), N-3/4(δN 5.1) for p-DMAPP and N-1(δN -84.1), N-2/5(δN -28.1), N-3/4(δN 4.2) for p-HPP, respectively. |
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| Keywords: | organic chemistry p-dimethylaminophenylpentazole p-hydroxyphenylpentazole synthesis NMR |
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