Preparation and Certification of Hydrogen in Titanium Alloy Standard Reference Materials

A series of three hydrogen in titanium alloy Standard Reference Materials (SRMs 2452, 2453, and 2454) was prepared with hydrogen mass fractions bracketing the hydrogen specification limit of 125?mg/kg. Commercial titanium alloy Ti6Al4V (6?pct aluminum and 4?pct vanadium) was heated under vacuum in a furnace to remove native hydrogen, then it was doped with a measured quantity of hydrogen. Prompt gamma-ray activation analysis was used to determine hydrogen in the degassed material and finished SRMs. A combination of preparation data and PGAA measurement was used to certify the hydrogen mass fraction of each. The certified hydrogen mass fractions are 62.5?mg/kg?±?1.6?mg/kg for SRM 2452, 114?mg/kg?±?5?mg/kg for SRM 2453, and 211?mg/kg?±?4?mg/kg for SRM 2454.