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钛酸酯偶联剂在碳酸钙填充PVC中的应用研究
引用本文:瞿雄伟,姬荣琴,潘明旺,张留成.钛酸酯偶联剂在碳酸钙填充PVC中的应用研究[J].河北工业大学学报,2001,30(1):84-88.
作者姓名:瞿雄伟  姬荣琴  潘明旺  张留成
作者单位:河北工业大学 化工学院,
基金项目:河北省自然科学基金项目资助!(201006)
摘    要:用红外光谱分析(FTIR)研究了钛酸酯偶联剂对碳酸填料的活化作用,探讨活化碳酸钙对填充PVC复合材料的力学性能和流变性能的影响。结果表明:碳酸钙经钛酸酯偶联剂处理,改善了其在复合材料中的分散性、流变性能,冲击强度比未处理碳酸钙的冲击强度提高了56%,并用扫描电子显微镜(SEM)观察了复合材料断面形貌,揭示形态结构与性能间的关系。

关 键 词:钛酸酯偶联剂  碳酸钙  PVC  流变行为  力学性能  红外光谱分析  填充塑料  聚氯乙烯
文章编号:1007-2373(2001)01-0084-05
修稿时间:2000年8月21日

Study on Application of Titanate Coupling Agents in CaCO3-filled PVC Composites
QU Xiong-wei,JI Rong-qin,PAN Ming-wang,ZHANG Liu-cheng.Study on Application of Titanate Coupling Agents in CaCO3-filled PVC Composites[J].Journal of Hebei University of Technology,2001,30(1):84-88.
Authors:QU Xiong-wei  JI Rong-qin  PAN Ming-wang  ZHANG Liu-cheng
Abstract:This paper studied the surface modification of light calcium carbonate (L-CaCO3) with titanate coupling agents by FTIR. The effects of activated L-CaCO3 on rhelogical behavior and mechanical properties of PVC composites were discussed. The results showed that the dispersion of L-CaCO3 in PVC and the rhelogical behavior of composites were improved by adding the coupling agent of titanate. The charpy impact strength of the L-CaCO3-filled PVC composite treated with NDZ 101 was increased by 56%, which Was demonstrated by examining the broken surface of specimen with SEM. The relationship between the morphology and properties established was useful for industrial producting.
Keywords:titanate coupling agent: light calcium carbonate: PVC: rhelogical behavior: mechanical properties
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