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Transparent conducting Nb-doped anatase TiO2 (TNO) thin films sputtered from various oxide targets
Authors:Naoomi Yamada  Taro Hitosugi  Ngoc Lam Huong Hoang  Shoichiro Nakao  Yasushi Hirose  Toshihiro Shimada  Tetsuya Hasegawa
Affiliation:a Kanagawa Academy of Science and Technology (KAST), Kawasaki 213-0012, Japan
b WPI Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
c Department of Chemistry, University of Tokyo, Tokyo 113-003, Japan
Abstract:Transparent conducting Nb-doped anatase TiO2 (TNO) epitaxial films were sputtered from TiO2-, Ti2O3-, and Ti-based targets at various oxygen partial pressures (Po2). Using the TiO2- and Ti2O3-based targets, highly conductive films showing a resistivity (ρ) of ~ 3 × 10− 4 Ω cm could be formed without postdeposition treatment. In the case of the TNO films formed from the Ti-based target, reductive annealing had to be carried out at a temperature of 600 °C to achieve similar resistivity values. Thus, the use of oxide targets is preferable to obtain as-grown transparent conducting TNO films. In particular, the Ti2O3-based target is practically advantageous, because it offers a wide range of optimal Po2 values at which ρ values of the order of 10− 4 Ω cm are achievable.
Keywords:Nb-doped TiO2   Anatase   Sputtering   Ti2O3   Transparent conducting oxides
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