Temperature-controlled microwave solid-state synthesis of Li3V2(PO4)3 as cathode materials for lithium batteries |
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Authors: | Gang Yang Haidong Liu Hongmei Ji Zhongzhong Chen Xuefan Jiang |
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Affiliation: | Jiangsu Laboratory of Advanced Functional Material, Changshu Institute of Technology, Changshu 215500, China |
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Abstract: | Monoclinic Li3V2(PO4)3 can be rapidly synthesized at 750 °C for 5 min (MW5m) by using temperature-controlled microwave solid-state synthesis method (TCMS). The carbon-free sample MW5m presents well electrochemical properties. In the cut-off voltage 3.0-4.3, MW5m presents a charge capacity 132 mAh g−1, almost equivalent to the reversible cycling of two lithium ions per Li3V2(PO4)3 formula unit (133 mAh g−1), and discharge capacity 126.4 mAh g−1. In the cut-off voltage 3.0-4.8 V, MW5m shows an initial discharge capacity of 183.4 mAh g−1, near to the theoretical discharge capacity. In the cycle performance, the capacity fade of Li3V2(PO4)3 is dependent on the cut-off voltage and the preparation method. |
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Keywords: | Lithium secondary batteries Cathode material Microwave solid-state synthesis Electrochemistry |
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