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Rheological,Thermodynamic, and Gas Solubility Properties of Phenylacetic Acid‐Based Deep Eutectic Solvents
Authors:Tausif Altamash  Mert Atilhan  Amal Aliyan  Ruh Ullah  Mustafa Nasser  Santiago Aparicio
Affiliation:1. Qatar University, Department of Chemical Engineering, Doha, Qatar;2. Texas A&M University at Qatar, Department of Chemical Engineering, Doha, Qatar;3. Qatar University, Gas Processing Research Center, Doha, Qatar;4. University of Burgos, Department of Chemistry, Burgos, Spain
Abstract:Choline chloride + phenylacetic acid‐based deep eutectic solvents are studied. Their most relevant experimental physicochemical properties at different mixing ratios together with the CO2 solubility data obtained in wide pressure and temperature ranges are reported. The presented materials exhibit a significant CO2 capture performance with low corrosion effect when compared with the most common amine‐based CO2 capture agents. Detailed rheological measurements are carried out and various models are applied to describe the dynamic flow behavior of the solvents. The CO2 absorption mechanism is evaluated by studying the behavior of the liquid gas and interface. Due to the advantages of low cost, nontoxicity, and favorable physical properties, these solvents are an environmentally promising alternative for effective CO2 capture technological applications.
Keywords:Carbon capture  Deep eutectic solvents  Gas solubility  Rheology  Thermodynamic properties
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