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UV/Fenton法降解四环素废水的试验研究
引用本文:汪艳宁,卢广守.UV/Fenton法降解四环素废水的试验研究[J].天津城市建设学院学报,2011(4):260-263.
作者姓名:汪艳宁  卢广守
作者单位:[1]天津城市建设学院环境与市政工程系,天津300384 [2]天津城市建设学院天津市水质科学与技术重点实验室,天津300384 [3]天津市建筑科学研究院天津市质量监督检验站第24站,天津300193
摘    要:分析了FeSO4和H2O2的初始浓度及溶液pH值对UV/Fenton法降解四环素废水的影响.结果表明四环素的初始浓度为25,mg/L时,降解四环素的最佳工况:FeSO4的初始浓度为0.05mmol/L,H2O2的初始浓度为10,mmol/L,pH值为2.5,在反应时间为60,min时,对四环素的去除率可达93.14%.另外,对自然光、太阳光、紫外光三种不同光照条件进行了对比试验,得出紫外光辐照下的四环素去除率最高,太阳光次之,自然光最小.

关 键 词:高级氧化反应  UV/Fenton  四环素  光氧化

Study on Degradation of Tetracycline Wastewater by UV/Fenton Process
WANG Yan-ning,a,b,LU Guang-ning.Study on Degradation of Tetracycline Wastewater by UV/Fenton Process[J].Journal of Tianjin Institute of Urban Construction,2011(4):260-263.
Authors:WANG Yan-ning  a  b  LU Guang-ning
Affiliation:WANG Yan-ning, LU Guang-ning (1a. Department of Environmental and Municipal Engineering, 1b. Tianjin Key Laboratory of Aquatic Science and Technology, TIUC, Tianjin 300384, China; 2. Tianjin No. 24 Station of Technology Supervision & Inspection, Tianjin Research Institute of Building Science, Tianjin 300193, China)
Abstract:The influences of initial concentrations of the FeSO4, H2O2 and solution pH values on the degradation of tetracycline wastewater by UV/Fenton process were analyzed. Experimental results indicate that when the initial concentration of tetracycline was 25 mg/L, the optimum operational conditions of the processes were as follows: the initial concentration 0.05 mmol/L FeSO4, 10 mmol/L H2O2, pH2.5. After 60 minutes' reaction, the tetracycline removal rate was 93.14%. In addition, comparative tests on varous lighting conditions (natural daylight, sunlight and UV-light) were conducted. The results show that the tetracycline removal rate was highest under UV irradiation, a little lower under sufllight, lowest under natural daylight.
Keywords:advanced oxidation reaction  UV/Fenton  tetracycline  photo oxidation
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