| 微波辅助合成1,3,5-三取代六氢均三嗪类化合物 |
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| 引用本文： | 余秦伟,李亚妮,杨建明,薛云娜,葛忠学,吕剑. 微波辅助合成1,3,5-三取代六氢均三嗪类化合物[J]. 火炸药学报, 2011, 34(6): 26-29 |
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| 作者姓名： | 余秦伟 李亚妮 杨建明 薛云娜 葛忠学 吕剑 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 摘 要： | 在微波作用下,将不同有机腈与三聚甲醛反应合成出乙酰基-、丙酰基-、丁酰基-和苯甲酰基-1,3,5-三取代六氢均三嗪化合物.结果表明,微波作用可提高有机腈和三聚甲醛的反应速率,使反应在数十秒内完成.Br(o)nsted 酸是该反应的有效催化剂,反应收率较高.在微波作用不使用有机溶剂或循环利用有机溶剂条件下,有机腈与三聚甲...
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| 关 键 词： | 含能材料 微波 六氢化均三嗪 合成 |
Microwave Assistant Synthesis of 1,3,5-Tri-substituted Perhydro-s-triazines |
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| YU Qin-wei , LI Ya-ni , YANG Jian-ming , XUE Yun-na , GE Zhong-xue , Lü Jian. Microwave Assistant Synthesis of 1,3,5-Tri-substituted Perhydro-s-triazines[J]. Chinese Journal of Explosives & Propellants, 2011, 34(6): 26-29 |
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| Authors: | YU Qin-wei LI Ya-ni YANG Jian-ming XUE Yun-na GE Zhong-xue Lü Jian |
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| Affiliation: | YU Qin-wei,LI Ya-ni,YANG Jian-ming,XUE Yun-na,GE Zhong-xue,Lü Jian(Xi′an Modern Chemistry Research Institute,Xi′an 710065,China) |
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| Abstract: | The reaction of synthesizing 1,3,5-tri-substituted perhydro-s-triazines(TSPSTs) under microwave irradiation from nitriles R-C≡N(R=CH3,CH3CH2,CH3CH2CH2,C6H5)and 1,3,5-trioxane was investigated.The results showed that the microwave irradiation increased the reaction rates of nitriles and 1,3,5-trioxane and the reaction times were not beyond one hundred seconds.The strong Brnsted acids are effective catalysts for the reaction of nitriles and 1,3,5-trioxane with high yields.Using the reaction of nitriles and 1,3,5-trioxane without solvent or with solvent recycling under micowave irradiation is a novel method of synthesizing TSPSTs. |
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| Keywords: | energetic materials microwave perhydro-s-triazines synthesis |
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