| 烯丙基-联苯醚的合成及其共聚合 |
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| 引用本文： | 赵梦奇,田玉川,司马义·努尔拉.烯丙基-联苯醚的合成及其共聚合[J].合成树脂及塑料,2012,29(2):38-41,68. |
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| 作者姓名： | 赵梦奇 田玉川 司马义·努尔拉 |
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| 作者单位： | 新疆大学化学化工学院,石油天然气精细化工教育部和自治区重点实验室,新疆维吾尔自治区乌鲁木齐市830046 |
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| 摘 要： | 采用相转移催化法合成了一种新型的非离子型疏水单体烯丙基-联苯醚(ABE),通过傅里叶变换红外光谱、核磁共振氢谱等表征了单体的结构,并分别用乳液法和溶液法合成了ABE-丙烯酰胺(AM)-丙烯酸(AA)三元共聚物。溶液法合成的共聚物为细小颗粒,平均粒径为900 nm左右,比表面积为14.93 m2/g,水溶性较差;而乳液法制备的共聚物水溶性较好,特性黏数大,达37.69 dL/g,耐热性能优良。
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| 关 键 词： | 烯丙基-联苯醚 共聚合 表征 热稳定性 |
Synthesis of allyl biphenyl ether and its copolymerization |
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| Zhao Mengqi
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Tian Yuchuan
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Ismayil Nurulla.Synthesis of allyl biphenyl ether and its copolymerization[J].China Synthetic Resin and Plastics,2012,29(2):38-41,68. |
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| Authors: | Zhao Mengqi Tian Yuchuan Ismayil Nurulla |
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| Affiliation: | Zhao Mengqi,Tian Yuchuan,Ismayil Nurulla(Key Laboratory of Oil and Gas Fine Chemicals,Ministry of Education and Xinjiang Uyghur Autonomous Region,College of Chemistry and Chemical Engineering,Xinjiang University,Urumqi 830046,China) |
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| Abstract: | A novel non-ionic hydrophobic monomer,allyl biphenyl ether(ABE),was synthesized via phase-transfer catalysis.The monomer′s structure was characterized by Fourier transform infrared spectroscopy(FTIR) and hydrogen nuclear magnetic resonance(1H-NMR).A terpolymer was prepared from ABE,acrylic acid and acrylamide through emulsion polymerization and solution polymerization,respectively.The terpolymer synthesized with solution polymerization process took the shape of tiny particles that possessed average size of about 900 nm and specific surface area of 14.93 m2/g.The terpolymer exhibited inferior solubility in water.In contrast,the terpolymer prepared with emulsion polymerization process had good solubility in water,high intrinsic viscosity of 37.69 dL/g and superior thermal stability. |
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| Keywords: | allyl biphenyl ether copolymerization characterization thermal stability |
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