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AgIn共掺杂(AgIn)xPb1-2xTe化合物的合成及热电传输性能
引用本文:刘海君,鄢永高,唐新峰,尹玲玲,张清杰. AgIn共掺杂(AgIn)xPb1-2xTe化合物的合成及热电传输性能[J]. 半导体学报, 2007, 28(5): 705-710
作者姓名:刘海君  鄢永高  唐新峰  尹玲玲  张清杰
作者单位:武汉理工大学材料复合新技术国家重点实验室,武汉,430070
基金项目:国家自然科学基金,高等学校科技创新工程重大培育项目
摘    要:用高温熔融法合成了Ag和In共掺的单相n型(AgIn)xPb1-2xTe化合物,研究了(AgIn)掺杂量x对(Ag-In)xPb1-2xTe(x=0.01~0.05)物相组成及热电性能的影响.结果表明:掺杂量x≤0.04时得到单相四元化合物,x=0.05时样品中出现了组成为AgInTe2第二相;(AgIn)xPb1-2xTe化合物的Seebeck系数随着x增加而增大,电导率随着掺杂量x增加而降低;化合物的热导率随着掺杂量x增大而减小;当x=0.01时,(AgIn)xPb1-2xTe化合物的热电性能指数值最大,在800K时达到1.1.

关 键 词:(AgIn)xPb1-2xTe  合成  热电性能
收稿时间:2015-08-18
修稿时间:2006-11-28

Synthesis and Thermoelectric Properties of AgIn Codoped(AgIn)xPb1-2xTe Compounds
Liu Haijun, Yan Yonggao, Tang Xinfeng, Yin Lingling, Zhang Qingjie. Synthesis and Thermoelectric Properties of AgIn Codoped (AgIn)xPb1-2xTe Compounds[J]. Journal of Semiconductors, 2007, In Press. Liu H J, Yan Y G, Tang X F, Yin L L, Zhang Q J. Synthesis and Thermoelectric Properties of AgIn Codoped (AgIn)xPb1-2xTe Compounds[J]. Chin. J. Semicond., 2007, 28(5): 705.Export: BibTex EndNote
Authors:Liu Haijun  Yan Yonggao  Tang Xinfeng  Yin Lingling  Zhang Qingjie
Affiliation:State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China;State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China
Abstract:Single-phase n-type (AgIn)xPb1-2xTe compounds were synthesized using the melting reaction method.Influences of (AgIn) substituting for Pb on the constituent phases and thermoelectric properties of the (AgIn)xPb1-2xTe(x=0.01~0.05) were investigated.Results indicate that single phase compound is obtained when the (AgIn) substitution fraction x≤0.04.However,the second phase (AgInTe2) was observed in the sample withx=0.05.The Seebeck coefficient increases gradually with the increasing of the (AgIn) substitution fraction x,and the electrical conductivity of the compounds decreases with the increasing of x.Thermal conductivity decreases with the increasing of x.In all of the n-type (AgIn)xPb1-2xTe compounds,(AgIn)0.01Pb0.98Te compound has the greatest ZT value,reaching 1.1 at 800K.
Keywords:(AgIn)xPb1-2xTe   synthesis   thermoelectric properties
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