p-Chlorostyrene oligomers. Preparation,structure, and stereochemistry |
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Authors: | Jitsuo Kiji Hisatoshi Konishi Tamon Okano Eijiro Ajiki |
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Abstract: | The dimer and trimer obtained by the pyrolysis of poly(p-chlorostyrene) were 2,4-di(p-chlorophenyl)-1-butene and 2,4,6-tri(p-chlorophenyl)-1-hexene, respectively, while those obtained by the cationic oligomerization of p-chlorostyrene were trans-1,3-di(p-chlorophenyl)-1-butene and a diastereomeric pair of trans-1,3,5-tri-(p-chlorophenyl)-1-hexene. |
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