Optical properties of CH3NH3PbX3 (X = halogen) and their mixed-halide crystals |
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Authors: | N. Kitazawa Y. Watanabe Y. Nakamura |
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Affiliation: | (1) Department of Materials Science and Engineering, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa, 239-8686, Japan |
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Abstract: | Thin films of microcrystalline CH3NH3PbX3 (X = halogen) as well as their mixed-halide crystals were fabricated by the spin-coating technique, and their optical properties were investigated. X-ray diffraction investigation revealed that CH3NH3PbBr3 – x Clx (x = 0–3) were successfully formed on glass substrate self-assembly and oriented with the a-axis. Owing to due to their large exciton binding energy, these materials showed clear exciton absorption and free-exciton emission in the visible region at room temperature. Replacing Br with CI made it possible to control the band structure of these materials. As a result, the peak position of the exciton band shifted continuously towards blue region with increasing the CI content in the films. |
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