| 超支化聚(酰胺-酯)的合成及其光致变色性能研究 |
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| 引用本文： | 秦红,周建,安业娜,祁波.超支化聚(酰胺-酯)的合成及其光致变色性能研究[J].胶体与聚合物,2010,28(4):174-177. |
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| 作者姓名： | 秦红 周建 安业娜 祁波 |
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| 作者单位： | 河北大学化学与环境科学学院,河北省保定市071002 |
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| 摘 要： | 采用丁二酸酐、三羟甲基氨基甲烷为主要原料,在冰水浴条件下合成AB_3型单体,然后进行熔融缩聚制得超支化聚(酰胺-酯)(HBP);再将含羧基的螺吡喃光致变色基元通过反应活性基团羧基与AB_3超支化聚合物末端羟基的反应而引入到AB_3超支化聚合物末端上,得到具有光致变色性能的超支化聚合物(MHBP)。利用红外、核磁等对其结构进行了表征,利用紫外可见分光谱对超支化聚合物光致变色性进行了研究。结果表明:MHBP同时具有超支化聚合物的性能和光致变色性能。
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| 关 键 词： | 超支化聚合物 聚(酰胺-酯) 光致变色 |
Synthesis and Photochromism of Hyperbranched Poly(amide-ester) |
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| QIN Hong,ZHOU Jian,AN Yena,QI Bo.Synthesis and Photochromism of Hyperbranched Poly(amide-ester)[J].Chinese Journal of Colloid and Polymer,2010,28(4):174-177. |
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| Authors: | QIN Hong ZHOU Jian AN Yena QI Bo |
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| Affiliation: | (College of Chemistry and Environmental Science Hebei University,Baoding 071002) |
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| Abstract: | The hyperbranched poly（amide ester） and Indoline spiropyran photochromism were synthesized.The products were characterized by FTIR,~1H-NMR,UV techniques,and so on.Then,the end groups of the hyperbranched poly（amide-ester） were modified with Indoline spiropyran photochromism.The hyperbranched polymer（MHBP） was characterized by UV techniques.The results showed that MHBP was provided with hyperbranched polymer properties and photochromic properties simultaneously. |
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| Keywords: | Hyperbranched Polymer Poly（amide-ester） Photochromism |
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