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负载型共掺杂TiO2对城市废水的日光降解作用
引用本文:薛茹君,代新营,黄静.负载型共掺杂TiO2对城市废水的日光降解作用[J].淮南工业学院学报,2011(4):9-12.
作者姓名:薛茹君  代新营  黄静
作者单位:安徽理工大学化学工程学院,安徽淮南232001
基金项目:安徽省教育厅自然科学研究重大基金资助项目(ZD200903); 淮南市科技专项基金资助项目
摘    要:采用过渡金属与稀土离子共掺杂对TiO2/漂珠光催化剂进行改性,以提高其日光催化性能。以紫外-可见漫反射光谱研究了粉煤灰微珠负载共掺杂TiO2光催化剂的光吸收性能;考察了催化剂对城市废水的日光催化降解性能。实验结果表明:所制备的各种共掺杂TiO2/漂珠催化剂在太阳光照射下对有机废水有较好的降解效果;废水的pH=6.5、催化剂投入量为3.5g/L时,其降解率最大,日光照射5 h后,降解率可以达到85.12%(CODCr)和73.4%(NH3-N)。催化剂使用后可以活化再生2次。

关 键 词:日光降解  共掺杂TiO2  城市废水

Performance of Sunlight Catalytic Degradation of Urban Waste water of Carried Co-doped TiO_2
XUE Ru-jun,DAI Xin-ying,HUANG Jing.Performance of Sunlight Catalytic Degradation of Urban Waste water of Carried Co-doped TiO_2[J].Journal of Huainan Institute of Technology(Natural Science),2011(4):9-12.
Authors:XUE Ru-jun  DAI Xin-ying  HUANG Jing
Affiliation:(School of Chemical Engineering,Anhui University of Science and Technology,Huainan Anhui 232001,China)
Abstract:TiO2/cenosphere photocatalyst was modified via co-doped with transition metal ions and rare earth metal ions to raise its sunlight catalytic activity.Sunlight absorption performances of the co-doped TiO2/cenosphere photocatalysts were investigated by UV-visible spectrophotometer.The degradation capacities of city waste water on the co-doped TiO2/cenosphere photocatalysts were studied.The results show that the sunlight photocatalytic activity of the co-doped TiO2/cenosphere was better.They possess the best degradation capacity when the pH value of waste water = 6.5 and the catalyst dosage at 3.5 g/L.The degradation rate of city waste water could reach 85.12%(CODCr) and 73.4%(NH3-N) after 5 h sunlight irradiation.The used-up photocatalyst could be reactivated 2 times.
Keywords:sunlight catalytic degradation  co-doped TiO2  urban wastewater
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