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非离子改性可水分散多异氰酸酯的制备与性能
引用本文:纪凤龙,王秋娣,李国荣,涂伟萍,刘其海,谢亦富,黄佩坚.非离子改性可水分散多异氰酸酯的制备与性能[J].现代涂料与涂装,2014(6):1-4.
作者姓名:纪凤龙  王秋娣  李国荣  涂伟萍  刘其海  谢亦富  黄佩坚
作者单位:[1]广州秀珀化工股份有限公司,广州511495 [2]华南理工大学化学与化工学院,广州510641
摘    要:采用聚乙二醇单甲醚(MPEG)对脂肪族多异氰酸酯进行亲水改性,研究了MPEG的相对分子质量、用量和合成工艺对可水分散多异氰酸酯固化剂的异氰酸酯(NCO)基团含量、黏度、水分散性及其对双组分水性聚氨酯涂料性能的影响。比较了形成氨基甲酸酯和形成脲基甲酸酯的改性路线的特点。

关 键 词:可水分散性  多异氰酸酯  双组分水性聚氨酯

Preparation of Nonionic Modified Water Dispersible Polyisocyanate and Its Property
JI Feng-long,WANG Qiu-di,LI Guo-rong,TU Wei-ping,LIU Qi-hai,XIE Yi-fu,HUANG Pei-jian.Preparation of Nonionic Modified Water Dispersible Polyisocyanate and Its Property[J].Modern Paint and Finishing,2014(6):1-4.
Authors:JI Feng-long  WANG Qiu-di  LI Guo-rong  TU Wei-ping  LIU Qi-hai  XIE Yi-fu  HUANG Pei-jian
Affiliation:1.Guangzhou Supe Chemical Co., Ltd., Guangzhou 511495, China; 2. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641,China )
Abstract:Abstract: The methoxypolyethylene glycols (MPEG) were employed to modify aliphatic polyisocyanates. The influences of the molecular weight and amount of MPEG and different synthesis processes on the content of isocyanate (NCO) groups, viscosity, water dispersibility of the resultant modified polyisocyanates and the properties of two-component waterborne polyurethane coatings were investigated. The water dispersible polyisocyanates bearing urethane groups and those containing allophanate groups were compared.
Keywords:water dispersible  polyisocyanate  two-component waterborne polyurethanes
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