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Synthesis and Optical Properties of Rare-Earth–Aluminum Oxide Glasses
Authors:J. K. Richard Weber   Johan G. Abadie   Thomas S. Key  Kirsten Hiera   Paul C. Nordine   Ronald W. Waynant  Ilko K. Ilev
Affiliation:Containerless Research, Inc., Evanston, Illinois 60201;Center for Devices and Radiological Health, U.S. Food and Drug Administration, Rockville, Maryland 20857
Abstract:Single-phase glasses containing 37.5 mol% Y2O3, 7 mol% La2O3, and 1 mol% Pr, Ho, Nd, Er, Sm, Tm, Eu, or Yb oxide substituted for part of the Y2O3 were synthesized by containerless melting. The spectral transmission and absorption cross sections of the glasses were determined at wavelengths from 360 to 3300 nm. The electronic transitions were broadened compared with results obtained in a crystalline yttrium aluminum garnet (YAG) host. The infrared transmission of the host glass extended to 6000 nm. The optical and physicochemical properties of these glasses are well suited for optical device applications.
Keywords:optical materials/properties    rare earths    glass    aluminates
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