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钛铁矿(FeTiO3)粉末的氧化过程中的物相转变、微观形貌及其氧化机制
引用本文:肖玮,鲁雄刚,邹星礼,危雪梅,丁伟中.钛铁矿(FeTiO3)粉末的氧化过程中的物相转变、微观形貌及其氧化机制[J].中国有色金属学会会刊,2013,23(8):2439-2445.
作者姓名:肖玮  鲁雄刚  邹星礼  危雪梅  丁伟中
作者单位:上海大学 上海市现代冶金与材料制备重点实验室,上海,200072
摘    要:探讨钛铁矿氧化过程中的物相转化、形貌改变及其氧化机理。在700~800°C时,钛铁矿(FeTiO3)转变为赤铁矿(Fe2O3)和金红石(TiO2),当温度高于900°C时,三价铁板钛矿开始形成。原始的钛铁矿粉末呈现顺磁性,但是经过中温(800~850°C)氧化后,氧化产物呈现弱铁磁性。同时,讨论钛铁矿的氧化机理。通过对微结构的观察,发现在中温氧化过程中颗粒表面出现大量微孔,其在氧化过程中能够强化氧的传质。

关 键 词:钛铁矿  物相转变  微观形貌  氧化机理
收稿时间:21 June 2012

Phase transitions,micro-morphology and its oxidation mechanism in oxidation of ilmenite (FeTiO3) powder
Wei XIAO,Xiong-gang LU,Xing-li ZOU,Xue-mei WEI,Wei-zhong DING.Phase transitions,micro-morphology and its oxidation mechanism in oxidation of ilmenite (FeTiO3) powder[J].Transactions of Nonferrous Metals Society of China,2013,23(8):2439-2445.
Authors:Wei XIAO  Xiong-gang LU  Xing-li ZOU  Xue-mei WEI  Wei-zhong DING
Affiliation:Shanghai Key Laboratory of Modern Metallurgy and Materials Processing, Shanghai University, Shanghai 200072, China
Abstract:Phase transitions, morphology changes, and oxidation mechanism of the ilmenite oxidation process were investigated. FeTiO3 transforms to hematite and rutile when oxidation at 700–800 °C, and pseudobrookite is formed when the oxidation temperature reaches 900 °C. The initial ilmenite powder exhibits paramagnetism; however, after being oxidized at the intermediate temperature (800–850 °C), the oxidation product exhibits weak ferromagnetism. The oxidation mechanism was discussed. The microstructure observations show that a lot of micro-pores emerge on the surfaces of ilmenite particles at the intermediate temperature, which is deemed to be capable of enhancing the mass transfer of oxygen during oxidation.
Keywords:ilmenite  phase transitions  micro-morphology  oxidation mechanism
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