| 淀粉接枝丙烯腈合成高吸水树脂的工艺研究 |
| |
| 引用本文： | 田桂芝,张颖,王东军,李璐,佟天宇.淀粉接枝丙烯腈合成高吸水树脂的工艺研究[J].应用化工,2007,36(4):380-382. |
| |
| 作者姓名： | 田桂芝 张颖 王东军 李璐 佟天宇 |
| |
| 作者单位： | 抚顺职业技术学院,化工系,辽宁,抚顺,113006 |
| |
| 摘 要： | 以淀粉接枝丙烯腈制备高吸水树脂(SAP)。考查了丙烯腈用量、引发剂用量、聚合时间、聚合温度、水解时间对产品纯度及吸水率的影响。结果表明,合成SAP的最佳工艺条件为:丙烯腈用量10.5 g,为淀粉用量的3.5倍,引发剂用量0.08 g,占淀粉用量的2.67%,聚合时间2.5 h,聚合温度30℃,水解时间2.5 h。甲醇作沉淀剂,调整冷却速度,合成树脂吸水率达1 200倍以上。
|
| 关 键 词： | 吸水树脂 淀粉 丙烯腈 合成 |
| 文章编号： | 1671-3206(2007)04-0380-03 |
| 修稿时间： | 2006-12-11 |
Study on the process of starch combined with acrylonitrile to form SAP |
| |
| TIAN Gui-zhi,ZHANG Ying,WANGDong-jun,LI Lu,TONG Tian-yu.Study on the process of starch combined with acrylonitrile to form SAP[J].Applied chemical industry,2007,36(4):380-382. |
| |
| Authors: | TIAN Gui-zhi ZHANG Ying WANGDong-jun LI Lu TONG Tian-yu |
| |
| Affiliation: | Department of Chemical Engineering, Fushun Vocational Technical Institute, Fushun 113006, China |
| |
| Abstract: | Preparation of SAP using starch and acrylonitrile as raw materials has been studied.The effect of the amount of acrylonitrile,the amount of initiator,polymerization time,polymerization temperature,hydrolysis time on the purity and absorbing water rate of the product were observed.Optimum conditions of synthesizing technology were determined,10.5 g monomer,3.5 times of the amount of starch,0.08 g initiator,2.67% of the amount of starch,polymerization time is 2.5 h,polymerization temperature is 30 ℃,hydrolysis time is 2.5 h.Methanol as precipitating agent appropriately controlling cooling rate can make the absorbing water rate of absorbent polymer up to 1 200 times. |
| |
| Keywords: | absorbent resin starch acrylonitrile synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
