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Photoluminesence studies of CdTe/SnO2 and CdTe/CdS heterojunctions: The influence of oxygen and the CdCl2 heat treatment
Authors:Sergiu Vatavu  Hehong Zhao  Iuliana CaramanChris Ferekides
Affiliation:
  • a Faculty of Physics, Moldova State University, 60 A. Mateevici str., Chisinau, MD 2009, Republic of Moldova
  • b Electrical Engineering Department, University of South Florida, Mail Point: ENB118, 4202 East Fowler Ave., Tampa, FL 33620, USA
  • c Engineering Department, University of Bacau, 157 Calea Marasesti, 600115 Bacau, Romania
  • d Surya Power Inc., 2001 Gateway Place, 150W, San Jose, CA, 95110, USA
  • Abstract:The influence of oxygen and annealing in the presence of CdCl2 on the photoluminescence (PL) spectra of CdTe, component of SnO2/CdTe heterojunction (HJ), has been studied in a temperature range of 17-100 K. The changes in the photoluminescence spectra were studied as a function of excitation intensity. Analysis of the PL spectra was carried out with considerations of spectra obtained from CdS/CdTe heterojunctions. CdTe side PL (SnO2/CdTe HJ) consisted of 1.450 eV-DA defect band and 1.243 eV band (17 K). Annealing resulted in the disappearance of 1.243 eV band in oxygen containing samples. Interface PL for the unannealed samples consisted of mainly the 1.264 eV and a trace of the defect band. The CdCl2 treatment is responsible for an almost symmetrical 1.416 eV band.
    Keywords:CdS  CdTe  Heterojunction  Oxygen  Photoluminescence (PL)
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