| 微管内环己烷氧化反应研究进展 |
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| 引用本文： | 王磊,葛倩,朱明乔.微管内环己烷氧化反应研究进展[J].合成纤维工业,2013,36(3):44-48. |
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| 作者姓名： | 王磊 葛倩 朱明乔 |
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| 作者单位： | 浙江大学化学工程与生物工程学系,浙江杭州,310027 |
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| 基金项目： | 浙江省自然科学基金，浙江省自然科学基金杰出青年团队，工业控制技术国家重点实验室开放课题基金，浙江省重大科技计划项目，广西石化资源加工及过程强化技术重点实验室开放课题基金 |
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| 摘 要： | 介绍了微管反应器和微管内环己烷氧化反应的特点;详述了微管内环己烷无催化氧化的反应工艺、微管内气液流动情况、反应机理以及微管内壁负载催化剂的环己烷催化氧化反应工艺;指出无催化及内壁涂覆催化剂的微管内环己烷氧化反应在改善反应的安全性、强化气液传质效果和提高催化性能等方面具有较大优势,微管内壁负载纳米金催化剂的反应器形式在环己烷氧化反应中前景看好。
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| 关 键 词： | 环己烷 氧化反应 微管反应器 催化剂涂覆 |
Research progress of cyclohexane oxidation in a micro-capillary reactor |
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| Wang Lei
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Ge Qian
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Zhu Mingqiao.Research progress of cyclohexane oxidation in a micro-capillary reactor[J].China Synthetic Fiber Industry,2013,36(3):44-48. |
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| Authors: | Wang Lei Ge Qian Zhu Mingqiao |
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| Affiliation: | (Department of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027) |
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| Abstract: | A micro-capillary reactor and the characteristics of cyclohexane oxidation in the micro-capillary reactor were introduced.The reaction process and mechanism of non-catalyst cyclohexane oxidation in the micro-capillary reactor were described in details,as was the flow characteristics of gas-liquid phase in the micro-capillary reactor.And the technology of cyclohexane oxidation catalyzed with the supported catalyst coated on the wall of the micro-capillary reactor was also described.The technologies of cyclohexane oxidation without catalysts or with the catalyst coated on the wall of the micro capillary reactor were significantly superior in improving the reaction safety,intensifying the gas-liquid mass transfer and bettering the catalyst performance.The reactors with supported nano-gold catalysts on the wall of the micro-capillary reactor were expected to have an attractive prospect for cyclohexane oxidation. |
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| Keywords: | cyclohexane oxidation micro-capillary reactor catalyst coating |
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