| 有机硅低聚体改性丙烯酸酯树脂的合成 |
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| 引用本文： | 宋君荣,王久芬,郑冬青.有机硅低聚体改性丙烯酸酯树脂的合成[J].中国胶粘剂,2006,15(12):23-25. |
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| 作者姓名： | 宋君荣 王久芬 郑冬青 |
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| 作者单位： | 中北大学化工与环境学院化学工程系,山西省太原市,030051 |
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| 摘 要： | 以偶氮二异丁睛(AIBN)为引发剂,选择甲基丙烯酸丁酯、丙烯酸和丙烯酸丁酯等单体共聚,合成丙烯酸酯树脂;选择-苯基三乙氧基硅烷与二甲基二乙氧基硅烷为单体进行水解缩聚,合成有机硅树脂低聚体;通过有机硅树脂低聚体与丙烯酸酯树脂的接枝反应,合成有机硅低聚体改性丙烯酸酯树脂,并对影响改性树脂性能的重要因素进行了探讨,找出了合成改性树脂的最优条件。
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| 关 键 词： | 有机硅低聚体 丙烯酸酯树脂 溶液聚合 |
| 文章编号： | 1004-2849(2006)12-0023-03 |
| 收稿时间： | 2006-09-15 |
| 修稿时间： | 2006年9月15日 |
Synthesis of acrylate resin modified by siloxane-oligomer |
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| SONG Jun-rong,WANG Jiu-fen,ZHENG Dong-qing.Synthesis of acrylate resin modified by siloxane-oligomer[J].China Adhesives,2006,15(12):23-25. |
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| Authors: | SONG Jun-rong WANG Jiu-fen ZHENG Dong-qing |
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| Affiliation: | Department of Chemical and Environment Institute Chemistry Engineering,North University of China, Taiyuan 030051 ,China |
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| Abstract: | In this paper,siloxane-acrylate resin was obtained by the branch reaction of acrylate resin and siloxane -oligomer. Acrylate resin was synthesized by the polymerization of MBA, AA and BA with AIBN as initiator,siloxane-oligomer was prepared by the hydrolysis and polycondensation reaction of phenyltriethoxysilane and dimethyldiethoxylsilane.The important factors for influence on properties of siloxane-acrylate resin were discussed,the optimal formulas for resin were obtained. |
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| Keywords: | siloxane-oligomer acrylate resin solution polymerization |
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