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预先电沉积ZnO/Zn(OH)2对烧结镍电极的影响
引用本文:LUO Ping,罗萍,闫慧青,鲁文东,呙成,李会娟,焦萌,周德瑞.预先电沉积ZnO/Zn(OH)2对烧结镍电极的影响[J].电源技术,2007,31(4):315-317.
作者姓名:LUO Ping  罗萍  闫慧青  鲁文东  呙成  李会娟  焦萌  周德瑞
作者单位:河北工业大学,应用化学系,天津,300130;中国电子科技集团公司,第十八研究所,天津,300381;哈尔滨工业大学,应用化学系,黑龙江,哈尔滨,150001;河北工业大学,应用化学系,天津,300130;中国电子科技集团公司,第十八研究所,天津,300381;哈尔滨工业大学,应用化学系,黑龙江,哈尔滨,150001
摘    要:在烧结镍基体表面,预先电沉积一层ZnO/Zn(OH)2薄膜,然后通过电化浸渍制得镍电极,研究了预先电沉积ZnO/Zn(OH)2对烧结镍电极的影响.实验结果表明:与普通烧结镍电极相比,预先电沉积ZnO/Zn(OH)2,改善了烧结镍电极的大电流充放电性能和循环性能,增加了电极的可逆性,提高了电极的充电接受能力,同时减少了电极循环过程中的掉粉量和电极膨胀率,且当ZnO/Zn(OH)2的预先电沉积量为b%时,烧结镍电极的电极性能处于最佳.

关 键 词:预先电沉积  烧结镍电极  充电电压  放电电压  循环寿命
文章编号:1002-087X(2007)04-0315-03
修稿时间:2006年9月6日

Effects of electrochemical deposition of zinc-oxides and/or zinc-hydroxides on sintered nickel electrode
LUO Ping.Effects of electrochemical deposition of zinc-oxides and/or zinc-hydroxides on sintered nickel electrode[J].Chinese Journal of Power Sources,2007,31(4):315-317.
Authors:LUO Ping
Abstract:The sintered nickel electrode was prepared by electrochemical dipping after pre-deposited the zinc-oxides and/or zinc-hydroxides on the electrode substrate.The effects of electrochemical deposition of zinc-oxides and/or zinc-hydroxides on sintered nickel electrode were studied.The results indicate that the electrode prepared by the pre-deposition method shows a significant charge-discharge performance and cycle performance,increases the reversibility of electrode and charge acceptance at high current.It also can prevent some of the active material coming out of the porous nickel structure,and prevent the electrode swelling.The electrode with b%(by weight) of zinc-oxides and/or zinc-hydroxides pre-deposited has optimal electrode performance.
Keywords:pre-deposited  sintered nickel electrode  charge voltage  discharge voltage  cycle life
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