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Carbon monoxide induced desorption of alkanes and alkenes up to C8 after chemisorption of methane on platinum
Authors:H. Amariglio  M. Belgued  P. Paréja  A. Amariglio
Affiliation:(1) Laboratoire de Catalyse Hétérogène, Université de Nancy I, BP 239, 54 506 Vand"oelig"uvre-lès-Nancy Cedex, France
Abstract:CH4 homologation can proceed under reductive conditions by successive exposures of various supported metals to CH4 and H2. When a Pt/SiO2 catalyst is submitted to a CO dose after an exposure to CH4 at a moderate temperature, several hydrocarbons are released with a large proportion of olefins. It may therefore be concluded that C-C bonding processes take place during the mere exposure of platinum to CH4 at moderate temperatures.
Keywords:methane  chemisorption  methane chemisorption  methane oligomerization  precursors of higher hydrocarbons  hydrocarbonaceous adspecies
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