Comment on radical polymerization mechanism of vinyl benzoate |
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| Authors: | M Kamachi J Satoh D J Liaw |
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| Affiliation: | (1) Department of Polymer Science, Faculty of Science, Osaka University, Toyonaka, 560 Osaka, Japan |
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| Abstract: | Summary The elementary rate constants for the radical polymerization of vinyl acetate and vinyl benzoate have been determined in various
aromatic solvents and ethyl acetate. The kp values for vinyl benzoate are larger than those for vinyl acetate in all solvents,
although methyl affinities of both monomer were similar. These results show that the poly(vinyl benzoate) radical is more
reactive than the poly(vinyl acetate) radical. |
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