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碳纳米管-双(4-氨基苯基醚)衍生物的合成
引用本文:柯刚,韦星船,刘晓国,刘自力,冯勇跃. 碳纳米管-双(4-氨基苯基醚)衍生物的合成[J]. 化工新型材料, 2009, 37(7)
作者姓名:柯刚  韦星船  刘晓国  刘自力  冯勇跃
作者单位:广州大学工程抗震研究中心,教育部工程抗震减震与结构安全重点实验室,广州,510405;广州大学化学化工学院,广州,510006;武汉大学分析测试中心,武汉,430072
摘    要:采用双(4-氨基苯基醚)(ODA)修饰多壁碳纳米管(MWNTs),合成出结构新颖的衍生物MWNT-ODA.FTIR分析表明,ODA分子通过酰胺键与MWNTs共价键接.MWNT-ODA中MWNTs的含量约为43.5%(质量含量),并可溶于N,N'-二甲基甲酰胺等极性有机溶剂.该衍生物可作为碳纳米管进一步功能化的基础材料,而且在高分子交联剂等方面具有潜在的应用前景.

关 键 词:碳纳米管  双(4-氨基苯基醚)  衍生物  合成

Synthesis of derivative of di- (4-aminophenyl) ether with carbon nanotubes
Ke Gang,Wei Xingchuan,Liu Xiaoguo,Liu Zili,Feng Yongyue. Synthesis of derivative of di- (4-aminophenyl) ether with carbon nanotubes[J]. New Chemical Materials, 2009, 37(7)
Authors:Ke Gang  Wei Xingchuan  Liu Xiaoguo  Liu Zili  Feng Yongyue
Abstract:Multi-walled carbon nanotubes (MWNTs) were covalently functionalized with di-(4-aminophenyl)ether (ODA). As a novel derivative of MWNTs, MWNT-ODA was characterized with FTIR. Results showed that the ODA molecules were attached to the MWNTs through amide linkages. Content of the MWNTs in the MWNT-ODA was about 43. 5%, and the MWNT-ODA dissolved in polar organic solvents, such as DMF. The MWNT-ODA might be not only a base for further functionalization of the MWNTs, but also an useful candidate for cross-linking agent of polymers.
Keywords:MWNTs  di-(4-arninophenyl)ether  derivative  synthesis
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