CHEMICAL AND TECHNICAL ASPECTS OF HYDROFORMYLATION OF OLEFINS WITH SUPPORTED LIQUID-PHASE RHODIUM CATALYSTS期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

CHEMICAL AND TECHNICAL ASPECTS OF HYDROFORMYLATION OF OLEFINS WITH SUPPORTED LIQUID-PHASE RHODIUM CATALYSTS

Authors:	J.J.F. Scholten R. Van Hardeveld

Affiliation:	^a Department of Catalysis, DSM Central Laboratories, Geleen, MD, The Netherlands

Abstract:	Supported liquid-phase catalysts containing RhH(CO)(PPH₃)₃ dissolved in PPH₃ are used in the gas-phase hydroformylation of several olefins. Their activity in the hydroformylation of ethylene, propylene and the butenes is reported. Various physicochemical aspects of the rhodium SLP catalysts, such as the adsorptive withdrawal of the rhodium complexes by the supports, the activity of the rhodium complexes at the gas-liquid interface and the solubility of the reactants and products in the liquid part of the catalysts, are discussed. The results are presented of a bench-scale process study of the hydroformylation of propylene, from which the design parameters of a future plant are calculated.

Keywords:	Hydroformylation Olefins Supported
本文献已被 InformaWorld 等数据库收录！