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Corrosion behavior of alumina ceramics in aqueous HCl and H2SO4 solutions
Authors:Lidija ?urkovi?  Mirjana Fuduri? Jela?a
Affiliation:a Faculty of Mechanical Engineering and Naval Architecture, Ivana Lu?i?a 5, Zagreb, Croatia
b College for Safety, Ivana Lu?i?a 5, Croatia
c Faculty of Chemical Engineering and Technology, Maruli?ev trg 19, Zagreb, Croatia
Abstract:The corrosion behavior of cold isostatically pressed (CIP) high purity alumina ceramics in aqueous HCl and H2SO4 solutions with various concentrations has been studied simultaneously at room temperature (25 °C). Corrosion tests were also performed with 0.65 mol/l HCl and 0.37 mol/l H2SO4 solutions at 40, 55 and 70 °C for 48 h. Chemical stability was monitored by determining the amount of Al3+, Mg2+, Ca2+, Na+ Si4+ and Fe3+ ions eluted in different concentrations of HCl and H2SO4 solutions by means of atomic absorption spectrometry (AAS). By increasing the concentration from 0.37 to 6.5 mol/l, it was notified that the corrosion susceptibility in HCl and H2SO4 solutions for the CIP alumina specimens at room temperature decreases.
Keywords:A. Ceramic   B. Acid corrosion   B. Kinetic parameters
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